Beilstein J. Nanotechnol.2017,8, 2615–2624, doi:10.3762/bjnano.8.262
O2CCH2OMe− is generated, further following the first fragmentation route. However, at 1.3 eV the initial step is decarboxylation giving [AgCH2OMe(PPh3)], followed by Ag–P and Ag–C bond cleavages.
Keywords: DFT; DSC; FEBID; silver(I) carboxylate; solid-state structure; TGA; Introduction
Focused electron
silver(I) carboxylate [{AgO2CCH2OMe}n] (1), which gives [{AgO2CCH2OMe(PPh3)}n] (2), when treated with equimolar amounts of PPh3 (Scheme 1).
Coordination polymers 1 and 2 are colorless solids, which are stable towards air and moisture and hence can be safely handled under aerobe conditions. Silver
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Scheme 1:
Synthesis of [{AgO2CCH2OMe}n] (1) and [{AgO2CCH2OMe(PPh3)}n] (2).